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Ammonia bisulfate and ammonium sulfate are common chemical substances widely used in industrial production and laboratories. Although they have similar names, there are actually some obvious differences. The chemical formula of ammonium bisulfate is NH4HSO4, which is an acidic salt commonly used in the preparation of other ammonium salts and ammonia gas. The chemical formula of ammonium sulfate is NH4 2SO4, which is a neutral salt mainly used as fertilizer and industrial raw materials. From the perspective of chemical properties, the two have different acid-base properties, so there are also some differences in their uses. In addition, the solid crystallization of ammonium bisulfate is a colorless and transparent monoclinic crystal system, while ammonium sulfate is a white crystal. The difference in crystal morphology and appearance is also a significant characteristic of the difference between the two. Correctly distinguishing the characteristics and uses of ammonium hydrogen sulfate and ammonium sulfate in industrial production and laboratory applications is of great significance for ensuring the smooth progress of production and experiments. Therefore, it is necessary to understand the differences and characteristics of these two chemical substances. I hope this article can help readers better understand ammonia hydrogen sulfate and ammonia sulfate, and avoid confusion and errors during use.