[News & Trends]:Interpreting the Differences between High and Low Molecules of Polyisobutylene from a Chemical Structure Perspective

Polyisobutylene is an important synthetic polymer widely used in industry and daily life. According to different degrees of polymerization, polyisobutylene can be divided into two types: high molecular weight and low molecular weight. So, what is the difference between these two? Below is an analysis from the perspective of chemical structure


The main difference between high molecular weight and low molecular weight of polyisobutylene lies in the length of the molecular chain. The molecular weight of high molecular weight polyisobutene is relatively large, with more repeated units of isobutene monomers and longer molecular chains. Low molecular weight polyisobutylene has a smaller relative molecular weight and shorter molecular chains. This different molecular chain length directly affects the physical properties of polyisobutylene


The molecular chains of polymer polyisobutylene are longer, and the intermolecular forces are enhanced. This results in polymer polyisobutylene having a higher melting point and glass transition temperature. In contrast, low molecular weight polyisobutylene has a lower melting point and glass transition temperature due to its shorter molecular chains and weaker intermolecular interactions


In addition, the molecular chains of high molecular weight polyisobutylene are longer, which increases the hindrance to molecular movement. Therefore, compared to low molecular weight polyisobutylene, its viscosity is higher. This also means that the fluidity of polymer polyisobutylene is poor and difficult to process. On the contrary, low molecular weight polyisobutylene has shorter molecular chains, resulting in lower viscosity and better processing performance


In addition, due to the different lengths of molecular chains, the physical properties of high molecular weight polyisobutene and low molecular weight polyisobutene also differ. Polymer polyisobutylene typically has high tensile strength, elongation at break, and wear resistance, making it suitable for producing high-strength and durable materials. Low molecular weight polyisobutylene, on the other hand, has lower strength and toughness and is commonly used to make soft materials


In summary, the difference between high molecular weight and low molecular weight of polyisobutylene is mainly reflected in molecular chain length, physical properties, and processing performance. Polymer polyisobutylene has a longer molecular chain, high melting point, high viscosity, and high tensile strength; Low molecular weight polyisobutylene has a shorter molecular chain, lower melting point, lower viscosity, and better processing performance. Understanding these differences helps us choose the appropriate type of polyisobutylene in practical applications to meet different needs.